When a battery operates, not all energy goes into powering devices—some is inevitably lost as heat due to internal resistance and electrochemical processes. Managing this heat is essential for performance, lifespan, and safety, especially in large-format cells used in electric vehicles or grid storage.
Heat Generation in Batteries
Every battery generates heat during operation. The main sources include:
| Source | Description |
|---|
| Ohmic losses | Resistive heating from current flow |
| Reaction overpotentials | Energy lost at electrode interfaces |
| Concentration gradients | Entropic effects from lithium redistribution |
In small cells or at low currents, the generated heat may dissipate naturally. However, in high-power or large-capacity applications, heat can accumulate, leading to temperature rises that affect battery performance and accelerate degradation.
In extreme cases, excessive heat can trigger thermal runaway—a dangerous,
self-reinforcing cycle of overheating.
Thermal Model Types
Thermal models are coupled with electrochemical models (such as the Doyle-Fuller-Newman model): the electrochemical processes dictate how much heat is generated, while the battery temperature affects transport properties inside the cell.
Lumped Thermal Models
These treat the entire battery as having a uniform temperature.
Advantages:
- Simpler and computationally efficient
- Suitable for real-time battery management systems (BMS)
Best for:
- Systems where temperature gradients are minimal
- Applications requiring fast calculations
Spatially Distributed Models
These account for temperature variations within the battery.
Depending on the desired level of resolution, these models can capture:
- Temperature differences across the current collector or cell thickness
- Detailed variations within each battery layer
Best for:
- Large-format cells
- High-power applications where internal temperature gradients significantly impact performance and safety
Choosing the Right Model
| Model Type | Complexity | Accuracy | Use Case |
|---|
| Lumped | Low | Moderate | Real-time BMS control |
| Spatially distributed | High | High | Design and analysis |
In practice, many battery management systems use simplified models for real-time control, while more detailed models are employed for design and analysis.
Impact on Battery Aging
Temperature control isn’t just about efficiency—it directly influences battery aging. Elevated temperatures accelerate chemical degradation processes, leading to:
- Capacity fade
- Increased internal resistance
This brings us to the topic of State of Health (SoH) and battery degradation.